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氢化奎宁 1,4-(2,3-二氮杂萘)二醚

氢化奎宁 1,4-(2,3-二氮杂萘)二醚

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?氢化奎宁 1,4-(2,3-二氮杂萘)二醚名称


















中文名

氢化奎宁 1,4-(2,3-二氮杂萘)二醚
英文名

4-[(R)-[(2R,4S,5R)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]-(6-methoxyquinolin-4-yl)methoxy]-1-[(R)-[(2R,4R,5S)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]-(6-methoxyquinolin-4-yl)methoxy]phthalazine
中文别名


氢化奎宁1,4-(2,3-二氮杂萘)二醚 (DHQ)2PHAL




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手性催化剂




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氢化奎宁1,4-酞嗪二醚




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(DHQ)2PHAL 双羟化配体



英文别名
更多








?氢化奎宁 1,4-(2,3-二氮杂萘)二醚物理化学性质




































密度 1.3±0.1 g/cm3
熔点 178?C (dec.)
分子式 C48H54N6O4
分子量 778.980
精确质量 778.420654
PSA 94.96000
LogP 9.20
外观性状 固体;White to Light yellow powder to crystal
折射率 1.688
储存条件 存放于惰性气体之中;避免空气






?氢化奎宁 1,4-(2,3-二氮杂萘)二醚安全信息

































符号

GHS07


GHS07
信号词
Warning
危害声明
H317
警示性声明
P280
个人防护装备
Eyeshields;Faceshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
安全声明 (欧洲)
S22-S24/25
危险品运输编码 NONH for all modes of transport
WGK德国 3
海关编码 2933990090





?氢化奎宁 1,4-(2,3-二氮杂萘)二醚合成线路


















~%







氢化奎宁 1,4-(2,3-二氮杂萘)二醚结构式

氢化奎宁 1,4-(2,3-二…

140924-50-1






文献:Journal of Organic Chemistry, , vol. 57, # 10 p. 2768 – 2771







?氢化奎宁 1,4-(2,3-二氮杂萘)二醚上下游产品











氢化奎宁 1,4-(2,3-二氮杂萘)二醚上游产品? 2

氢化奎宁 1,4-(2,3-二氮杂萘)二醚下游产品? 0










?氢化奎宁 1,4-(2,3-二氮杂萘)二醚海关















海关编码 2933990090
中文概述 2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素 品名, 成分含量, 用途, 乌洛托品请注明外观, 6-己内酰胺请注明外观, 签约日期
Summary 2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%








?氢化奎宁 1,4-(2,3-二氮杂萘)二醚文献2

更多文献











De novo synthesis of 2-substituted syn-1,3-diols via an iterative asymmetric hydration strategy.

J. Org. Chem. 71 , 7741, (2006)

The enantioselective syntheses of several protected 4-substituted syn-3,5-dihydroxy carboxylic esters have been achieved from the corresponding achiral (E,E)- or (E,Z)-1,3-dienoates. The route relies …





Kapferer, Tobias; Brueckner, Reinhard

European J. Org. Chem. 9 , 2119-2133, (2006)







?氢化奎宁 1,4-(2,3-二氮杂萘)二醚英文别名







































(DHQ)2PHAL


MFCD00191975


(8a,9R,8”’a,9”’R)-9,9′-[Phthalazine-1,4-diylbis(oxy)]bis(6′-methoxy-10,11-dihydrocinchonan)


(8α,9R,8”’α,9”’R)-9,9′-[1,4-Phthalazinediylbis(oxy)]bis(6′-methoxy-10,11-dihydrocinchonan)


Cinchonan, 9,9′-[1,4-phthalazinediylbis(oxy)]bis[10,11-dihydro-6'-methoxy-, (8α,9R,8'''α,9'''R)-


4,5-Ethylenedithio-1,3-dithiol-2-one


(DHQ)PHAL


hydroquinine 1,4-phthalazinediyl diether


5,6-dihydro-[1,2]dithiolo[4,5-b][1,4]dithiin-2-one


(8α,9R,8”’α,9”’R)-9,9′-[Phthalazine-1,4-diylbis(oxy)]bis(6′-methoxy-10,11-dihydrocinchonan)








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