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洋艾素
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| 描述 |
Absinthin 是一种结构独特的三萜类化合物，这是艾草苦味高的原因。Absinthin 是苦味受体 hTAS2R46 的一种激动剂，它通过 hTAS2R46 介导的受体特异性机制降低组胺诱导的细胞内 Ca2+ 升高。 |
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| 相关类别 |
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| SMILES |
CC1=C[C@@]2([H])[C@]3([H])[C@]1([C@](OC4=O)([H])[C@@]([C@@H]4C)([H])CC[C@@]3(O)C)[C@]5([H])[C@@]2([H])[C@]([C@]6(O)C)([H])C([C@](OC7=O)([H])[C@@]([C@@H]7C)([H])CC6)=C5C |
| 参考文献 |
[1]. Zhang W, et al. Total synthesis of absinthin. J Am Chem Soc. 2005 Jan 12;127(1):18-9. [2]. Lachenmeier DW, et al. Absinthe–a review. Crit Rev Food Sci Nutr. 2006;46(5):365-77.
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| 密度 | 1.3±0.1 g/cm3 |
|---|---|
| 沸点 | 700.6±60.0 °C at 760 mmHg |
| 熔点 | 165-166℃ (dec.) |
| 分子式 | C30H40O6 |
| 分子量 | 496.635 |
| 闪点 | 230.8±26.4 °C |
| 精确质量 | 496.282501 |
| PSA | 93.06000 |
| LogP | 2.41 |
| 蒸汽压 | 0.0±5.0 mmHg at 25°C |
| 折射率 | 1.609 |
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~86%
洋艾素
1362-42-1
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文献：Zhang, Weihe; Luo, Shengjun; Fang, Fang; Chen, Qingshou; Hu, Hanwei; Jia, Xueshun; Zhai, Hongbin Journal of the American Chemical Society, 2005 , vol. 127, # 1 p. 18 – 19 |
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~%
洋艾素
1362-42-1
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文献：Journal of the American Chemical Society, , vol. 127, # 1 p. 18 – 19 |
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~%
洋艾素
1362-42-1
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文献：Journal of the American Chemical Society, , vol. 127, # 1 p. 18 – 19 |
|
~%
洋艾素
1362-42-1
|
|
文献：Journal of the American Chemical Society, , vol. 127, # 1 p. 18 – 19 |
|
~%
洋艾素
1362-42-1
|
|
文献：Journal of the American Chemical Society, , vol. 127, # 1 p. 18 – 19 |
|
~%
洋艾素
1362-42-1
|
|
文献：Journal of the American Chemical Society, , vol. 127, # 1 p. 18 – 19 |
|
~%
洋艾素
1362-42-1
|
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文献：Journal of the American Chemical Society, , vol. 127, # 1 p. 18 – 19 |
![(3S,3aS,6R,6aR,9bS)-3,6,9-trimethyl-2-oxo-2,3,3a,4,5,6,6a,9b-octahydroazuleno[4,5-b]furan-6-yl acetate结构式](https://www.chemsrc.com/caspic/462/832135-37-2.png)
![(3S,3aS,6R,6aR,9bS)-8-hydroxy-3,6,9-trimethyl-2-oxo-2,3,3a,4,5,6,6a,7,8,9b-decahydroazuleno[4,5-b]furan-6-yl acetate结构式](https://www.chemsrc.com/caspic/386/832135-39-4.png)
![(3S,3aS,6R,6aR,9bS)-3,6,9-trimethyl-8-((2-nitrophenyl)selanyl)-2-oxo-2,3,3a,4,5,6,6a,7,8,9b-decahydroazuleno[4,5-b]furan-6-yl acetate结构式](https://www.chemsrc.com/caspic/031/832135-40-7.png)
| 洋艾素上游产品? 7 | |
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| 洋艾素下游产品? 0 | |
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Sbsinthin |
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(1R,2R,5S,8S,9S,12S,13R,14S,15S,16R,17S,20S,21S,24S)-12,17-Dihydroxy-3,8,12,17,21,25-hexamethyl-6,23-dioxaheptacyclo[13.9.2.0.0.0.0.0]hexacosa-3,25-diene-7,22-dione |
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ABSINTHII TINCTURA |
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ABSYNTHIN |
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Absinthiin |
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Absynthine |
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2H-7,13b-Ethenofuro[2'',3'':4',5']azuleno[1',2':2,3]azuleno[4,5-b]furan-2,12(11H)-dione, 3,3a,4,5,6,6a,6b,7,7a,8,9,10,10a,13a,13c,14b-hexadecahydro-6,8-dihydroxy-3,6,8,11,14,15-hexamethyl-, (3S,3aS,6S,6aR,6bS,7S,7aR,8S,10aS,11S,13aS,13bR,13cR,14bS)- |
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