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蒙花苷

蒙花苷

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?蒙花苷名称


















中文名

蒙花苷
英文名

5-hydroxy-2-(4-methoxyphenyl)-7-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-[[(2R,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxymethyl]oxan-2-yl]oxychromen-4-one
中文别名


蒙花甙




|



野菊花提取物



英文别名
更多





?蒙花苷生物活性


































描述
Linarin (Buddleoside) 是从薄荷花提取物中分离得到的，选择性的抑制乙酰胆碱酯酶 (AChE)。
相关类别



SMILES

O=C(C=C(C1=CC=C(OC)C=C1)OC2=CC(O[C@@H]([C@@H]([C@@H](O)[C@@H]3O)O)O[C@@H]3CO[C@H](O[C@@H](C)[C@H](O)[C@H]4O)[C@@H]4O)=C5)C2=C5O
参考文献

[1]. P?ivi P. Oinonen,etc. Linarin, a selective acetylcholinesterase inhibitor from Mentha arvensis, Fitoterapia,Volume 77, Issue 6, 2006, Pages 429-434, ISSN 0367-326X






?蒙花苷物理化学性质









































密度 1.6±0.1 g/cm3
沸点 885.2±65.0 °C at 760 mmHg
熔点 258-260?C
分子式 C28H32O14
分子量 592.545
闪点 292.2±27.8 °C
精确质量 592.179199
PSA 217.97000
LogP 2.10
外观性状 白色至灰白色粉末
蒸汽压 0.0±0.3 mmHg at 25°C
折射率 1.694





?蒙花苷合成线路




















5-hydroxy-2-(4-methoxy-3-((1-phenyl-1H-tetrazol-5-yl)oxy)phenyl)-7-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-((((2R,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyltetrahydro-2H-pyran-2-yl)oxy)methyl)tetrahydro-2H-pyran-2-yl)oxy)-4H-chromen-4-one结构式

5-hydroxy-2-(4-…

771480-96-7




~54%







蒙花苷结构式

蒙花苷

480-36-4


文献：Quintin, Jerome; Lewin, Guy Journal of Natural Products, 2004 , vol. 67, # 9 p. 1624 – 1627





地奥司明结构式

地奥司明

520-27-4




~%







蒙花苷结构式

蒙花苷

480-36-4


文献：Quintin, Jerome; Lewin, Guy Journal of Natural Products, 2004 , vol. 67, # 9 p. 1624 – 1627





金合欢素结构式

金合欢素

480-44-4








acetone oxime hydrochloride结构式

acetone oxime h…

4154-21-6




~%







蒙花苷结构式

蒙花苷

480-36-4


文献：Zemplen; Bognar Chemische Berichte, 1941 , vol. 74, p. 1818,1821




















?蒙花苷英文别名

















































































Acaciin


4H-1-Benzopyran-4-one, 7-[[6-O-(6-deoxy-α-L-mannopyranosyl)-β-D-glucopyranosyl]oxy]-5-hydroxy-2-(4-methoxyphenyl)-


5-Hydroxy-2-(4-methoxyphenyl)-7-{[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-({[(2R,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyltetrahydro-2H-pyran-2-yl]oxy}methyl)tetrahydro-2H-pyran-2-yl]oxy}-4H-chromen-4-one


Buddleoglucoside


EINECS 207-547-6


Acacetin 7-rutinoside


5-Hydroxy-2-(4-methoxyphenyl)-4-oxo-4H-chromen-7-yl-6-O-(6-deoxy-α-L-mannopyranosyl)-β-D-glucopyranoside


Acacetin 7-O-rutinoside


Acacetin 7-O-α-L-rhamnopyranosyl-(16)-β-D-glucopyranoside


acacetin-7-O-ramnosyl-glucoside


linarin


Acacetin-7-O-β-D-rutinoside


5,7-Dihydroxy-4′-methoxyflavone-D-glucosido-L-rhamnoside


Acacetin-b-rutinoside


Linarigenin-glucoside


5-Hydroxy-2-(4-methoxyphenyl)-4-oxo-4H-chromen-7-yl 6-O-(6-deoxy-α-L-mannopyranosyl)-β-D-glucopyranoside


Acacetin-7-rutinoside


Buddleoflavonoloside


Linaric acid


7-[[6-O-(6-Deoxy-a-L-mannopyranosyl)-b-D-glucopyranosyl]oxy]-5-hydroxy-2-(4-methoxyphenyl)-4H-benzopyran-4-one


Acacetin-7-O-rutinoside


Buddleoside


apigenin-4′-methylether-7-O-rutinoside


MFCD00151178








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